Wednesday 13 August 2014

Silicate Structure

Nesosilicates  (Island Silicates)  
Oxygens atoms are not shared with other SiO4-4 tetrahedrons. Ratio between Si & O is 1:4. The basic structural unit is SiO4-4. Eg. Olivine and Garnet group (Mg,Fe)2SiO4.
The atomic structure of nesosilicates are generally dense which cause the mineral of this group to have high specific gravity and hardness. Crystal system is generally equidimensional and have poor cleavage.



Sorosilicates  ( Double Island Silicatesy )
 
One oxygens is shared with another tetrahedron.Si:O is 2:7,The basic structural unit is Si2O7-6. Eg. Epidote group (Si2O7)

Cyclosilicates (Ring Silicates)


Two oxygens are shared and the structure is arranged in a ring, such as that shown here, Si:O is 1:3. Si6O18-12. Eg.  Beryl - Be3Al2Si6O18.                                                         




 Inosilicates (Single Chain Silicates)

If two of the oxygens are shared in a way to make long single chains of linked SiO4 tetrahedra, we get the single chain silicates or inosilicates. In this case the basic structural unit is Si2O6-4 or SiO3-2.  Eg. pyroxene group, like the orthopyroxenes (Mg,Fe)SiO3 or the clinopyroxenes Ca(Mg,Fe)Si2O6.

Inosilicates (Double Chain Silicates )
If two chains are linked together so that each tetrahedral group shares 3 of its oxygens, we can from double chains, with the basic structural group being Si4O11-6. Eg. amphibole group like tremolite - ferroactinolite series - Ca2(Mg,Fe)5Si8O22(OH)2.                                
Phyllosilicates (Sheet Silicates)



3 oxygens are shared, basic structural group is Si2O5-2. Eg. micas, clay minerals, chlorite, talc, and serpentine minerals. A good example is biotite - K(Mg,Fe)3(AlSi3)O10(OH)2.  Note that in this structure, Al is substituting for Si in one of the tetrahedral groups.




Tectosilicates (Framework Silicates)

All oxygens are shared with another SiO4 tetrahedron, The basic structural  SiO2.  The minerals quartz, cristobalite, and tridymite all are based on this structure.  If some of the Si+4 ions are replaced by Al+3 then this produces a charge imbalance and allows for other ions to be found coordinated in different arrangements within the framework structure.  Thus, the feldspar and feldspathoid minerals are also based on the tectosilicate framework.



minerallogy

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